Yes, I think that is possible (I haven't tested my solution so I don't know for sure).

I would start by creating an error log that records any time a WinAutomation job fails.  From the console, select Tools->Options->Error Handling, and check the box "Write Event to Text File".  Then type in the directory to save the text file to.

Next, create a job with two actions.  The first action is the "Take Screenshot" action in the "System" category; select Capture: "Entire Screen" and Save Screen Shot to: "File" (I'm not sure what format to use; look at the file produced to see what is best).  The second action is "Send Email" with the screenshot file attached.   Finally, set up a trigger for the job--right click on the job, select "Edit Triggers"->"Add New Trigger"->"File Monitor Trigger" and select the log file from the first step.

Hope this helps!

Andrew

 The above-mentioned solution will work absolutely perfect, but there is an alternative that you can use:

Instead of writing to a text file, you can use the "Run Another Job" option in the Error Handling tab of the Options window of WinAutomation console. This way, you will not have to directly involve any text files, and your screenshot job will be executed directly whenever an exception occurs. Furthermore, you can always override the error handling setup for a specific job (and for example execute a different job instead of the default that will not send a screenshot but will write to a log file) by going to the "Job Properties" of the specific job (right click on it -> Edit Job Properties in the console window) and select "Override Default Options" in the "Error Handling" tab.